Who Wants to Be a Cartoon Millionaire? (episode 1)

This was the first episode in the series.

Smiffy
Smiffy was the first contestant to get to the £1,000 mark in the hot seat but, being a complete thick-head, he got the first question wrong.

Fatty Fudge
Fatty Fudge was the second contestant to get to the £1,000 mark.

Sidney
Sidney was the first contestant to get to the £2,000 mark.

Ken Bahn
Ken Bahn was the first contestant to get to the £3,000 mark.

Sgt. Slipper
Sgt. Slipper was the first contestant to get to the £5,000 mark.

Dennis the Menace
Dennis was the second contestant to get to the £5,000 mark

Fatty Fudge's Son
Fatty Fudge's Son was the first contestant to get the £20,000 mark.

Ted Shackleford
Ted Shackleford was the first contestant to get the £40,000 mark.